GB6851-2008

pH primary reagent - General rules for certification

pH基准试剂定值通则

GB 6851-2008 est une norme nationale chinoise obligatoire en vigueur : pH primary reagent - General rules for certification. Secteur : Électronique. Thème principal : Méthodes d’essai. Entrée en vigueur : 1 juin 2009.

L’applicabilité dépend du périmètre du produit, de la voie de certification, des avis des autorités et des règles de transition. Demandez une traduction ou vérifiez la source avant d’utiliser cette fiche pour une décision de conformité.

Aperçu de conformité

Cet aperçu n’est actuellement disponible qu’en anglais.

Champ d’application

This standard applies to the certification and value determination of pH primary reagents and the preparation of pH standard buffer solutions at 25°C. It is specifically designed for chemical reagent manufacturers and metrology laboratories involved in the calibration of high-precision pH meters. It is not applicable to general industrial pH buffering agents not used for certified instrument calibration.

Exigences techniques

GB 6851-2008 establishes the general rules for determining the pH value of primary reagents using a double hydrogen electrode cell with liquid junction. The standard mandates specific preparation methods for various buffer solutions, including potassium hydrogen phthalate, potassium dihydrogen phosphate, and sodium tetraborate mixtures. A key requirement is the strict control of experimental conditions, including the use of high-purity hydrogen gas and Grade 2 laboratory water as specified in GB/T 6682. Manufacturers must ensure that the residual liquid junction potential is minimized to an acceptable threshold to maintain measurement integrity. Furthermore, the standard outlines the requirements for the expanded uncertainty of the pH standard buffer solutions. It defines the acceptable limits of precision for the final certified pH values, ensuring traceability to national metrological standards.

Méthodes d’essai

The primary testing method involves a comparative measurement using a double hydrogen electrode cell with a liquid junction. The procedure requires monitoring the cell's electromotive force (EMF) at a strictly controlled temperature of 25.0°C ± 0.1°C until equilibrium is reached. Additionally, the standard details the preparation and treatment of platinum/palladium hydrogen electrodes and specific salt bridges, as outlined in the normative appendices.

Questions fréquentes

What products are regulated under GB 6851-2008?

This standard regulates the certification of pH primary reagents and the preparation of pH standard buffer solutions used for the calibration of pH meters in China.

Are there any updates from the previous version of GB 6851-2008?

The 2008 version updated terminology, such as changing "primary pH reagent" to "pH primary reference material," and introduced the calculation of expanded uncertainty for pH standard buffer solutions, replacing the older GB 6851-1986.

How does GB 6851-2008 differ from ISO standards?

GB 6851-2008 is specifically tailored for China's national metrology framework, defining strict localized procedures and mandatory apparatus setups for pH value certification at 25°C, whereas ISO standards generally provide broader international guidelines.

The summary above provides a high-level overview of GB 6851-2008. To ensure complete compliance for your products entering the Chinese market, a precise and professional translation of the full technical specifications is essential. Purchase our high-quality English translation of GB 6851-2008 today to access all detailed parameters, tables, and testing procedures.

Indications d’applicabilité

Type: Méthode
CCS: G60
ICS: 71.040.30
Autorité compétente: Ministry of Industry and Information Technology
Comité technique: Ministry of Industry and Information Technology

Relations

Remplace:GB 6851-1986